Direct proof of use
The clearest coalition-side record is a U.S. Army account of a September 18, 2010 firefight at Shege East Afghan National Police Checkpoint in Kunar province. The article says International Security Assistance Forces and Afghan National Police answered insurgent fire with small arms, heavy machine-gun fire, and mortar fire, and then identifies 120 mm white phosphorus mortar rounds fired toward a nearby ridgeline where insurgents were located.
Insurgent-side evidence is documented separately. Military.com reproduced a CENTCOM/ISAF summary of reported insurgent white phosphorus attacks and caches in Afghanistan; one listed event says an ISAF road-clearance patrol found an IED rigged with one 120 mm white phosphorus round in Sabari District, Khost province, on September 15, 2008.
Sources: Coalition Forces Beat Attack on Afghan Checkpoint, Willy Pete in the Stan
Timeline
The CENTCOM-derived incident list places insurgent white phosphorus activity across several years of the war, but most entries identify 81 mm, 82 mm, 107 mm, or 122 mm munitions rather than 120 mm rounds. The source's 120 mm entry is the September 2008 Sabari District IED discovery.
The September 2010 Kunar report is the dated source that directly places 120 mm white phosphorus mortar rounds in coalition fire support during a checkpoint firefight.
Sources: Willy Pete in the Stan, Coalition Forces Beat Attack on Afghan Checkpoint
Operational role
In the Kunar event, 120 mm white phosphorus ammunition was used as part of mortar fire during a defensive fight at an Afghan police checkpoint. The reporting places the rounds on a ridgeline occupied by insurgents and pairs the fire with ISAF and Afghan police small-arms and heavy-machine-gun responses.
For Taliban and allied militant use, the cited record supports fielding and improvised use rather than a named 120 mm mortar firing event. The Sabari District entry describes a 120 mm white phosphorus round incorporated into an IED; the same incident list also records other insurgent white phosphorus indirect-fire attacks, caches, and unexploded-ordnance finds without always tying those events to 120 mm ammunition.
Sources: Coalition Forces Beat Attack on Afghan Checkpoint, Willy Pete in the Stan